Physical, chemical and biological characteristics of water
Quality Of Water
Characteristics Of Water:
I) Physical Characteristics:
·
Turbidity:
·
It
is caused by suspended materials such as clay, silt or some other finally
divided organic and inorganic matter. Turbidity is also due to presence of
bacteria, algae, protozoa, fungi. Expressed in ppm (or mg/l)
·
Standard
until is that which is produced by 1 mg of finely divided silica (Fullers earth)
in 1litre of distilled water.
·
Measured
on “Silica Scale”
·
Permissible
limit for potable water: 5 to 10 ppm
·
Measured
by: Turbidity meters
a) Jackson Turbid meter: Used to measure high turbidity (>
25 ppm) ----(JTU)
b) Baylis Turbid meter: Precisely record even low turbidity
values (of the order of 0 to 2 ppm) --- BTU
c) Nephelometer: Commonly used for turbidity of range
of 0 to 1 ppm – (NTU & FTU) –Formazan polymer is standard reference
suspension.
Turbidity
is the measure of resistance to the passage of light through water.
·
Color:
·
It
is caused by dissolved organic matters from decaying vegetation or some
inorganic-colored soils, growth of algae, metallic ions (Fe and Mn).
·
Measured
by comparing the color of water sample with other standard glass tubes (Nessler
tubes)
·
Measured
by platinum Cobalt Method (Measured on Platinum Cobalt Scale)
·
Permissible
limit: 5 to 20 ppm.
·
Measured
by Tintometer.
·
Taste & Odor:
·
Due
to dissolved organic matter or inorganic salts, dissolved gases etc.
·
Threshold
number is the standard unit for measuring.
Taste is expressed as FIN (Flavor threshold
Number)
Odor is expressed as TON
(Threshold Odor Number)
TON= Dilution ratio
Dilution Ratio= (A+B)/A
A= Vol. of raw water sample
B= Vol. of distilled water used
for dilution.
Permissible Limit: 1 to 3.
The odor changes with
temperature.
It is tested normally at 200
C to 250 C
Odor is measured by an apparatus
called osmoscope.
Osmoscope:
The osmoscope is graduated with P0 values
from 0 to 5.
P0 value of 0 indicates ‘no
perceptible odor’
P0 value of 5 indicates
‘extremely strong odor’
·
Temperature: 100C
is desirable.
·
Specific Conductivity: To know the dissolved salt content. Determined by ionic water tester.
Impurities
in water:
1) Suspended impurities: They cause turbidity. The
concentration of suspended impurities is measured by turbidity.
E.g.: silt,
clay, bacteria, fungi, algae.
2) Colloidal impurities: These are finely divided dispersion
of solid particles, not visible to the naked eye. These impurities if
associated with organic matter having bacteria becomes the chief source of
epidemic.
3) Dissolved impurities: It includes organic compounds,
inorganic salts and gases. The following are various dissolved impurities and
their effects.
a) Salts: CaCl2 , MgCl2 , CO3
, HCO3 , They cause hardness and alkalinity in water.
b) Metals: Iron causes red color, Manganese causes brown
color.
c) Lead and arsenic: It cause poisoning.
d) Gases: Oxygen causes corrosion of metals
·
Chlorine
and Ammonia cause bad taste and odor.
·
CO2
and Hydrogen sulphide cause acidity in water.
II) Chemical Characteristics:
1) Total solids, suspended solids and
dissolved solids:
·
Total
solids can be found by evaporating a sample of water and weighing the dry
residue left.
·
Suspended
solids can be found by filtering water sample through Whatman filter paper
No.44
·
Permissible
TDS limit: 500 to 1000 ppm.
Example
A 100 ml
water sample is drawn on to a empty dry container whose initial weight is
95.452 gm. After oven drying the sample at 1030C for 4 hours its
final weight measured to be 95.486 gm. Then total solid’s concentration in
mg/l.
Sol: Total Solids = w2-w2/v
x 106
W2
= final weight in gm,
W1
= initial weight in gm,
V = volume
of water sample in ml
= 95.486 – 95.452/100 x 106 =340
mg/l
2) pH value of water: It indicates hydrogen ion
concentration in water.
·
pH
= log10 (1/H+),
if pH > 7 it is
alkaline: if pH<7 it is acidic.
·
Alkalinity
is caused by bicarbonates (HCO3) of Ca and Mg and carbonates (CO3),
hydroxides (OH) of Ca, Mg, k, Na.
·
Acidity
is caused by Mineral Acids, free CO2, Sulphide of Fe &
Aluminum.
·
Alkalinity Effects: Incrustation and sediment deposit in pipelines and difficult in
chlorination.
·
Acidity Effects: Tuberculation & Corrosion of pipe lines.
·
Permissible
limit: 6.6 to 8.5
·
pH
is measured by potentiometer and Calorimetric method.
3) Hardness:
A characteristic which prevents formation of lather or foam with soap.
Effects of hardness:
Scaling of boilers, greater soap consumption,
corrosion and incrustation of pipe lines, food becomes tasteless etc.,
Types of Hardness:
1. Carbonate Hardness (CH)
2. Non-Carbonate Hardness (NCH)
·
Temporary or carbonate hardness: Caused by HCO3 and CO3 of
Ca & Mg.
·
Can
be removed to some extent by simple boiling or removed fully by addition of
lime.
·
Permanent or non-Carbonate hardness: Caused by SO4, Cl, NO3 of
Ca & Mg.
·
Can
be removed by water softening methods such as Lime soda process,
Demineralization process and Zeolite process.
Permissible
limits: For boiler
feed waters<75 ppm.
For
drinking purpose, between 75 & 115 ppm.
If Hardness
is <75 ppm is called ‘soft’
If Hardness
is >200 ppm is called ‘Hard’
Measurement:
Measured in terms of p p m or mg/lit of CaCO3
·
Measured
by EDTA test (Ethylene Diamine Tetrameric Acid test). In the titration process,
Eri chrome black T is used to show the end of titration.
·
After
determining number of Ca & Mg ions present in water by titration process
with versa nates solution hardness is estimated as follows;
Total
Hardness: in mg/l
as CaCO3
= [Ca in
mg/l x Equivalent wt. of CaCO3/ Equivalent wt. of Ca]
+ [Mg in
mg/ l x Equivalent wt. of CaCO3/ Equivalent wt. of Mg]
Combining
weight or equivalent weight = Molecular weight / valency
(Ca++=40;
Mg++ = 24; Sr++ = 87.6; CaCO3-- = 100; CO3
-- = 60; HCO3- =61; OH- = 17)
So, Total
Hardness = Ca++mg/l x (50/20) +Mg++mg/l x (50/12)
TH = CH
+NCH
If TH >
alkalinity, then CH = Alkalinity.
So, NCH =
TH – CH.
If TH <
Alkalinity, then CH = TH, NNCH = 0.
·
Hardness
is also expressed in degree of hardness.
·
One
British degree of hardness (Clark’s Scale) = 14.25 ppm of CaCO3
·
One
American degree of hardness = 17.15 ppm of CaCO3
= [HCO3
in mg/l x Equivalent wt. of CaCO3/Equivalent wt. of HCO3]
+ [CO3 in mg/l x Equivalent wt. of CO3]
So, Total
alkalinity = HCO3- mg/l x (50/61) + CO3- mg/l x (50/30)
4) Chloride content:
Present in
the form of Sodium Chloride. Imparts salty taste.
·
Permissible
limit: 250 mg/l. Presence of high quantity indicates pollution from sewage and
other human & industrial waste.
5) Nitrogen Content: Indicates presence of organic matter
and the extent to which it has undergone decomposition.
Different
forms:
i)
Free Ammonia: indicates
presence of undecomposed organic matter and it represents first stage
decomposition permissible limit: less than 0.15 ppm
ii) Albuminoid Nitrogen: Indicates decomposition of organic
matter has started, limit shall not exceed 0.3 mg/lit
iii) Nitrites: Indicates presence of partly decomposed
organic matter. Permissible limit: nil
iv) Nitrates: Indicates fully oxidized organic
matter. Permissible limit:< 45 ppm.
·
Excess
causes the disease called “Methemoglobinemia” (Blue baby disease)
·
Total
Kjeld ahi Nitrogen (TKN) = Free ammonia + organic nitrogen
6) Metals & Chemical Substances:
a) Iron & Manganese:
Permissible limit: iron < 0.3 ppm, Mn <
0.05 ppm.
·
Excess
iron & Mn cause discoloration of clothes washed in such water and
incrustation of water mains due to deposits.
b) Copper: Permissible limit – 1 to 3
mg/l.
·
Affects
human lungs and other respiratory organs.
c) Sulphide: Permissible < 250 mg/l
·
Causes
laxative effect on human body and diarrhea.
d) Fluoride:
·
Fluoride
< 1 ppm, cause formation of cavities in the teeth.
·
Fluoride
> 1.5 ppm causes Fluorosis (mottling and discoloration of teeth) and
deformation of bones.
·
Permissible
limit: between 1 ppm and 1.5 ppm.
7) Dissolved gases:
a) H2S: It gives bad taste and odor
b) CO2: Indicates biological activity and
causes corrosion in pipe lines.
c) Dissolved oxygen (D.O): To know the extent of pollution of
water.
·
Determined
by Winkler’s method.
·
Since
D.O is consumed by unstable organic matter, D.O less than its saturated level
indicates presence of organic matter, therefore pollution.
·
For
fresh river water saturation D.O at 200 C =9.2 mg/l.
·
Permissible
limit: For potable water should be between 5 to 10 ppm.
d) Nitrogen gas: Indicates presence of organic
matter.
8) Biochemical oxygen Demand (B.O.D): Permissible Limits: B.O.D. of safe
drinking water = Nil.
iii) Microscopic Characteristics:
·
To
study about the presence of Bacteria, virus, Algae, Protozoa.
·
Bacteria
is single celled organisms
Bacteria
(1 to 4 microns in size): Classification:
1) Non pathogenic bacteria: They are Harmless; e. g Escherichia
coliform or E-coli.
2) Pathogenic bacteria: They are harmful & causes water
borne disease.
·
Detection
of “E-Coli” indicates the probable presence of ‘pathogens’
·
E-Coli
bacteria is used as indicator organism.
Classification
based on shape:
1) Cocci – Sphere shaped bacteria
2) Bacilli – Rod shaped bacteria
3) Spirally – Twisted rod-shaped
bacteria
Classification
based on living conditions:
1) Aerobic bacteria: It survives in the presence of
Oxygen
2) Anaerobic bacteria: It survives in the absence of Oxygen
3) Facultative bacteria: Survives with or without Oxygen.
To
detect and measure coliform bacteria, the following tests are available.
a) Total count test: In this test bacteria are cultivated
on specially prepared medium of agar for different dilutions of sample of water
with distilled water. The diluted sample is placed in an incubator for
specified time at specified temperature. The bacteria colonies so formed are
counted and results are computed per 100 ml
·
For
drinking water, the total count shall not be more than 1 per 100 ml
b) E- Coli test: Divided into
i)
Presumptive
test
ii) Confirmed test
iii) Completed test
In these
tests, if gas is produced after incubation, it is reported as +ve and further
tests are to be followed to confirm E- Coil. If no gas is produced it is
presumed that there is no bacteria and the test is treated as negative.
Recent
method. Sample is filtered through sterile membrane with pore size 5 to 10 mm. The
bacteria is retained on the membrane. The membrane is put in contact with
suitable nutrient. [ M- Endo’s medium] which inhibits growth of bacteria other
than coli from group. Then placed in incubator at prescribed conditions and the
visible colonies are counted with microscope.
MPN (Most Probable Number):
It is the
bacterial density which is most likely to be present in water. It is used to
report the amount of bacteria present.
· To
determine MPN, confirmed or completed tests results are required.
· Permissible
limits: MPN should be Nil.
Micro
Organic plants: These
are tiny plants.
E.g.: Algae, plankton etc.
· They
cause bad taste & odor and interface with smooth working of filter.
· To
control algae, copper sulphide chemical is mixed in water.
Protozoa:
These are
unicellular animals.
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